You DO NOT want to mess with the jet sizing, unless you know what you're doing and you have access to a wideband O2 to read the A/F. Safest way is to follow the manufacture suggestion on jet sizing for your application. It will be rich to keep your motor safe.
If you want optimum performance with your nitrous, take it to a tuner who knows Vipers and nitrous. Since you're in IL, you may want to contact TOOOFST.
When people tune for optimum performance, it's specific for their application, so it will most likely NOT work with your set up. You don't want to have a lean condition with nitrous.