In chemistry class, we learned that the higher octane has less engine knock properties, so it should burn better. I have always used the Amoco 93 octane gas here. And remember to fill up in the morning too. Since in the afternoon it is thought that the heat that is transferred to the ground heats up the gas enough to make it closer to the gaseous state, hence less dense. I don't know if this is true here, but it is in Italy. I do notice a difference in liters/cost.